《国外化学名著系列6》是2008年科学出版社出版的图书，作者是范立文。

本书内容涵来自盖此领域的最新研究成果，临床处理的具体细节，在过程控制、生物芯片、临床分析、环境科学等领域的示范性应用等，概述了光学传感技术在过去二十年各方面的发展，并对未来的趋势进行了展望。

• 书名 国外化学名著系列6
• 又名 工业、环境与诊断应用 industrial, environmental and diagnostic applications 
• 作者 范立文
• ISBN 9787030211859
• 类别 专著

内容简介

　　《国洲让岁型怕用米移程非去外化学名著系列6(影印版)》基于作者在教学及工来自业实践方面广泛的经验，探据来不到封讨了许多新的和旧的重要反应。每章均以基础知识开始，以最新的内容结束。《国外化学名著系列6(影印版360百科)》侧重于要领但也列举越掉单红模了许多实验室合成有机化学品的关宪决键工业流程和应用流程。全书涵盖烟令眼轮程差似精细化学品，大宗系异侵死化学品，聚合物，高技术聚合物，流补联脸药品，也包括重要的技巧和反应类型等。同时还介绍了一些反应过程、环境问题和案全问题。

目录

　　Preface

　　Acknowledgements

　　1. INTRODUCTION

　　1.1 CATALYSIS

　　1.2 HOMOGENEOUS CATALYSIS

　　1.3 维奏配讨随社袁烈穿零茶HISTORICAL NOTES ON HOMOGENEOUS CATALYSIS

　　1.4 CHARA飞益CTERISATION OF THE CATALYST

　　罗洲历源田检雨短何1.5 LIGAND EFFECTS

　　1.5.1 P送财号这蛋跑送稳跟表hosphines and phosphites: electronic effects

　　1.5.2 Phosphines and phosphites: steric effects

　　1.5.3 L冷纪侵厂全要练知inear Free Energy Relationships

　　1.5.4 Ph送阿飞处济专烟临osphines and phosphites: bite angle effects

　　1.6 LIGANDS ACCORDING TO DONOR ATOMS

　　1.6.1 Anionic and neutral hydrocarbyl groups

　　1.6.2 Alkoxy 序田and imido group创通商误极我s as anionic ligands

　　1.6.3 Amines, imines, oxazolines and related ligands

　　1.6.4 Pho厚种甚实由样委侵把sphines, phosphites, phosphorus amides, phospholes and related ligands

　　1.6.5 Carbenes, carbon monoxide

　　1.6.毫站剧所氢染6 Common anions

　　2. E位迅结止构陈造买赶LEMENTARY STEPS

　　2.1 CREATION OF A "VACANT" SITE AND CO-ORDINATION OF THE SUBSTRATE

　　2.2 INSERTION VERSUS MIGRATION

　　2.3 β-ELIMINATION AND DE-INSERTION

　　2.4 OXIDATIVE ADDITION

　　2.5 REDUCTIVE ELIMINATION

　　2.6 α-ELIMINATION REACTIONS

　　2.7 CYCLOADDITION REACTIONS INVOLVING A METAL

　　2.8 ACTIVATION OF A SUBSTRATE TOWARD NUCLEOPHILIC ATTACK

　　2.8.1 Alkenes

　　2.8.2 Alkynes

　　2.8.3 Carbon monoxide

　　2.8.4 Other substrates

　　2.9 a-BOND METATHESIS

　　2.10 DIHYDROGEN ACTIVATION

　　2.11 ACTIVATION BY LEWIS ACIDS

　　2.11.1 Diels-Alder additions

　　2.11.2 Epoxidation

　　2.11.3 Ester condensation

　　2.12 CARBON-TO-PHOSPHORUS BOND BREAKING

　　2.13 CARBON-TO-SULFUR BOND BREAKING

　　2.14 RADICAL REACTIONS

　　3. KINETICS

　　3.1 INTRODUCTION

　　3.2 TWO-STEP REACTION SCHEME

　　3.3 SIMPLIFICATIONS OF THE RATE EQUATION AND THE RATEDETERMINING STEP

　　3.4 DETERMINING THE SELECTIVITY

　　3.5 COLLECTION OF RATE DATA

　　3.6 IRREGULARITIES IN CATALYSIS

　　4. HYDROGENATION

　　4.1 WILKINSON'S CATALYST

　　4.2 ASYMMETRIC HYDROGENATION

　　4.2.1 Introduction

　　4.2.2 Cinnamic acid derivatives

　　4.2.3 Chloride versus weakly coordinating anions; alkylphosphines versus arylphosphines

　　4.2.4 Incubation times

　　4.3 OVERVIEW OF CHIRAL BIDENTATE LIGANDS

　　4.3.1 DUPHOS

　　4.3.2 BINAP catalysis

　　4.3.3 Chiral ferrocene based ligands

　　4.4 MONODENTATE LIGANDS

　　4.5 NON-LINEAR EFFECTS

　　4.6 HYDROGEN TRANSFER

　　5. ISOMERISATION

　　5.1 HYDROGEN SHIFTS

　　5.2 ASYMMETRIC ISOMERISATION

　　5.3 OXYGEN SHIFTS

　　6. CARBONYLATION OF METHANOL AND METHYL ACETATE

　　6.1 ACETIC ACID

　　6.2 PROCESS SCHEME MONSANTO PROCESS

　　6.3 ACETIC ANHYDRIDE

　　6.4 OTHER SYSTEMS

　　6.4.1 Higher alcohols

　　6.4.2 Phosphine-modified rhodium catalysts

　　6.4.3 Other metals

　　7. COBALT CATALYSED HYDROFORMYLATION

　　7.1 INTRODUCTION

　　7.2 THERMODYNAMICS

　　7.3 COBALT CATALYSED PROCESSES

　　7.4 COBALT CATALYSED PROCESSES FOR HIGHER ALKENES

　　7.5 KUHLMANN COBALT HYDROFORMYLATION PROCESS

　　7.6 PHOSPHINE MODIFIED COBALT CATALYSTS: THE SHELL PROCESS

　　7.7 COBALT CARBONYL PHOSPHINE COMPLEXES

　　7.7.1 Carbonyl species

　　7.7.2 Phosphine derivatives

　　8. RHODIUM CATALYSED HYDROFORMYLATION

　　8.1 INTRODUCTION

　　8.2 TRIPHENYLPHOSPHINE AS THE LIGAND

　　8.2.1 The mechanism

　　8.2.2 Ligand effects and kinetics

　　8.2.3 Regioselectivity

　　8.2.4 Process description, rhodium-tpp

　　8.2.5 Two-phase process, tppts: Ruhrchemie/Rhone-Poulenc

　　8.2.6 One-phase catalysis, two-phase separation

　　8.3 DIPHOSPHINES AS LIGANDS

　　8.3.1 Xantphos ligands: tuneable bite angles

　　8.4 PHOSPHITES AS LIGANDS

　　8.4.1 Electronic effects

　　8.4.2 Phosphites: steric effects

　　8.5 DIPHOSPHITES

　　8.6 ASYMMETRIC HYDROFORMYLATION

　　8.6.1 Rhodium catalysts: diphosphites

　　8.6.2 Rhodium catalysts: phosphine-phosphite ligands

　　9. ALKENE OLIGOMERISATION

　　9.1 INTRODUCTION

　　9.2 SHELL-HIGHER-OLEFINS-PROCESS

　　9.2.1 Oligomerisation

　　9.2.2 Separation

　　9.2.3 Purification, isomerisation, and metathesis

　　9.2.4 New catalysts

　　9.3 ETHENE TRIMERISATION

　　9.4 OTHER ALKENE OLIGOMERISATION REACTIONS

　　10. PROPENE POLYMERISATION

　　10.1 INTRODUCTION TO POLYMER CHEMISTRY

　　10.1.1 Introduction to Ziegler Natta polymerisation

　　10.1.2 History of homogeneous catalysts

　　10.2 MECHANISTIC INVESTIGATIONS

　　10.2.1 Chain-end control: syndiotactic polymers

　　10.2.2 Chain-end control: isotactic polymers

　　10.3 ANALYSIS BY13C NMR SPECTROSCOPY

　　10.3.1 Introduction

　　10.3.2 Chain-end control

　　10.3.3 Site control mechanism

　　10.4 THE DEVELOPMENT OF METALLOCENE CATALYSTS

　　10.4.1 Site control: isotactic polymers

　　10.4.2 Site control: syndiotactic polymers

　　10.4.3 Double stereoselection: chain-end and site control

　　10.5 AGOSTIC INTERACTIONS

　　10.6 THE EFFECT OF DIHYDROGEN

　　10.7 FURTHER WORK USING PROPENE AND OTHER ALKENES

　　10.8 NON-METALLOCENE ETM CATALYSTS

　　10.9 LATE TRANSITION METAL CATALYSTS

　　11. HYDROCYANATION OF ALKENES

　　11.1 THE ADIPONITRILE PROCESS

　　11.2 LIGAND EFFECTS

　　12. PALLADIUM CATALYSED CARBONYLATIONS OF ALKENES

　　12.1 INTRODUCTION

　　12.2 POLYKETONE

　　12.2.1 Background and history

　　12.2.2 Elementary steps: initiation

　　12.2.3 Elementary steps: migration reactions

　　12.2.4 Elementary steps: chain termination, chain transfer

　　12.2.5 Elementary steps: ester formation as chain termination

　　12.3 LIGAND EFFECTS ON CHAIN LENGTH

　　12.3.1 Polymers

　　12.3.2 Ligand effects on chain length: Propanoate

　　12.3.3 Ligand effects on chain length: Oligomers

　　12.4 ETHENE/PROPENE/CO TERPOLYMERS

　　12.5 STEREOSELECTIVE STYRENE/CO COPOLYMERS

　　13. PALLADIUM CATALYSED CROSS-COUPLING REACTIONS

　　13.1 INTRODUCTION

　　13.2 ALLYLIC ALKYLATION

　　13.3 HECK REACTION

　　13.4 CROSS-COUPLING REACTION

　　13.5 HETEROATOM-CARBON BOND FORMATION

　　13.6 SUZUKI REACTION

　　14. EPOXIDATION

　　14.1 ETHENE AND PROPENE OXIDE

　　14.2 ASYMMETRIC EPOXIDATION

　　14.2.1 Introduction

　　14.2.2 Katsuki-Sharpless asymmetric epoxidation

　　14.2.3 The Jacobsen asymmetric epoxidation

　　14.3 ASYMMETRIC HYDROXYLATION OF ALKENES WITH OSMIUM TETROXIDE

　　14.3.1 Stoichiometric reactions

　　14.3.2 Catalytic reactions

　　14.4 JACOBSEN ASYMMETRIC RING-OPENING OF EPOXIDES

　　14.5 EPOXIDATIONS WITH DIOXYGEN

　　15. OXIDATION WITH DIOXYGEN

　　15.1 INTRODUCTION

　　15.2 THE WACKIER REACTION

　　15.3 WACKIER TYPE REACTIONS

　　15.4 TEREPHTHALIC ACID

　　15.5 PPO

　　16. ALKENE METATHESIS

　　16.1 INTRODUCTION

　　16.2 THE MECHANISM

　　16.3 REACTION OVERVIEW

　　16.4 WELL-CHARACTERISED TUNGSTEN AND MOLYBDENUM CATALYSTS

　　16.5 RUTHENIUM CATALYSTS

　　16.6 STEREOCHEMISTRY

　　16.7 CATALYST DECOMPOSITION

　　16.8 ALKYNES

　　16.9 INDUSTRIAL APPLICATIONS

　　17. ENANTIOSELECTIVE CYCLOPROPANATION

　　17.1 INTRODUCTION

　　17.2 COPPER CATALYSTS

　　17.3 RHODIUM CATALYSTS

　　17.3.1 Introduction

　　17.3.2 Examples of rhodium catalysts

　　18. HYDROSILYLATION

　　18.1 INTRODUCTION

　　18.2 PLATINUM CATALYSTS

　　18.3 ASYMMETRIC PALLADIUM CATALYSTS

　　18.4 RHODIUM CATALYSTS FOR ASYMMETRIC KETONE REDUCTION

　　19. C-H FUNCTIONALISATION

　　19.1 INTRODUCTION

　　19.2 ELECTRON-RICH METALS

　　19.3 HYDROGEN TRANSFER REACTIONS OF ALKANES

　　19.4 BORYLATION OF ALKANES

　　19.5 THE MURAI REACTION

　　19.6 CATALYTIC a-BOND METATHESIS

　　19.7 ELECTROPHILIC CATALYSTS

　　SUBJECT INDEX